Investigation of the Reduction of Nitric Oxides by CO and H2 on Pt-Mo Catalysts under Oxidizing Conditions
نویسندگان
چکیده
B [±] deformation factor cL [eq(H )/l] H ion exchange capacity related to catalyst volume ct [mol/l] total molar concentration Deff [m /s] effective transport coefficient D [m/s] transport coefficient in gel phase or liquid phase ÐDij [m /s] binary Maxwell-Stefan diffusion coefficient of pair i-j m1 [±] volumetric distribution ratio of component 1 N [±] number of components N1 [mol/(m 2 s)] molar flux density of component 1 q [g/g] solvent loading of polymer R [J/(mol K)] universal gas constant r [mol/(eq(H) s)] intrinsic rate constant reff [mol/(eq(H ) s)] effective reaction rate SV [m /m] specific external surface T [ C] temperature xi [±] mole fraction of component i
منابع مشابه
Kinetics and mechanism of the reduction of nitric oxides by H2 under lean-burn conditions on a Pt±Mo±Co/a-Al2O3 catalyst
The kinetics and the mechanism of the selective reduction of nitric oxides (NOx) by hydrogen is studied on a trimetallic Pt± Mo±Co/a-Al2O3 catalyst under oxidising conditions. This system is interesting in view of an exhaust gas control of power plants or lean-burn cars. It can be shown that the NO dissociation is the crucial step, dominating the overall reaction behaviour and that it depends o...
متن کاملReaction-driven restructuring of Rh-Pd and Pt-Pd core-shell nanoparticles.
Heterogeneous catalysts that contain bimetallic nanoparticles may undergo segregation of the metals, driven by oxidizing and reducing environments. The structure and composition of core-shell Rh(0.5)Pd(0.5) and Pt(0.5)Pd(0.5) nanoparticle catalysts were studied in situ, during oxidizing, reducing, and catalytic reactions involving NO, O2, CO, and H2 by x-ray photoelectron spectroscopy at near-a...
متن کاملExploring the Synergistic Performance of a Pt-Rh/γ-Al2O3 Catalyst for the Reduction of NO with H2
Several researchers have shown that Pt-Rh bimetallic catalysts can perform synergistically for the NO/H2, NO/CO, CO/O2, and NO/CO/HC reactions [1-5]. Lakis and coworkers clarified some of the mystery surrounding the synergistic performance of Pt-Rh catalysts for the NO + H2 reaction by using analytical electron microscopy (AEM) to show that the synergistic performance of a Pt(95%)Rh(5%)/γ-Al2O3...
متن کاملCATALYTIC REFORMING OF n-HEPTANE ON PLATINUM-TUNGSTEN SUPPORTED ON GAMMA-ALUMINA
The mono-metallic and bi-metallic catalysts have been prepared by impregnating with solutions containing a compound of H2PtCl6,WO3 and 1ml HCl (0.1 mol). It should be noted that the catalysts’ activity and selectivity have been determined under these conditions : 450-5000C ,and 15-25atm by H2. For converting n-heptane , the molar ratio H2/C7H16 is 5 , and LHSV is 1.5ml/h. It has been proved tha...
متن کاملExperimental and Kinetic Study of CO Oxidation Over LaFe1-xCuxO3 (x=0, 0.2, 0.4, 0.6) Perovskite-Type Oxides
In this paper, catalytic oxidation of CO over the LaFe1-xCuxO3 (x= 0, 0.2, 0.4, 0.6) perovskite-type oxides was investigated. The catalysts were synthesized by sol-gel method and characterized by XRD, BET, FT-IR, H2-TPR and SEM methods. The catalytic activity of catalysts was tested in catalytic oxidation of CO. XRD patterns confirmed the synthesized perovskites to be single-phase perovskite-ty...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 1998