Investigation of the Reduction of Nitric Oxides by CO and H2 on Pt-Mo Catalysts under Oxidizing Conditions

نویسندگان

  • Ragnar Lübke
  • Gerhard Emig
  • Albert Renken
چکیده

B [±] deformation factor cL [eq(H )/l] H ion exchange capacity related to catalyst volume ct [mol/l] total molar concentration Deff [m /s] effective transport coefficient D [m/s] transport coefficient in gel phase or liquid phase ÐDij [m /s] binary Maxwell-Stefan diffusion coefficient of pair i-j m1 [±] volumetric distribution ratio of component 1 N [±] number of components N1 [mol/(m 2 s)] molar flux density of component 1 q [g/g] solvent loading of polymer R [J/(mol K)] universal gas constant r [mol/(eq(H) s)] intrinsic rate constant reff [mol/(eq(H ) s)] effective reaction rate SV [m /m] specific external surface T [ C] temperature xi [±] mole fraction of component i

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Kinetics and mechanism of the reduction of nitric oxides by H2 under lean-burn conditions on a Pt±Mo±Co/a-Al2O3 catalyst

The kinetics and the mechanism of the selective reduction of nitric oxides (NOx) by hydrogen is studied on a trimetallic Pt± Mo±Co/a-Al2O3 catalyst under oxidising conditions. This system is interesting in view of an exhaust gas control of power plants or lean-burn cars. It can be shown that the NO dissociation is the crucial step, dominating the overall reaction behaviour and that it depends o...

متن کامل

Reaction-driven restructuring of Rh-Pd and Pt-Pd core-shell nanoparticles.

Heterogeneous catalysts that contain bimetallic nanoparticles may undergo segregation of the metals, driven by oxidizing and reducing environments. The structure and composition of core-shell Rh(0.5)Pd(0.5) and Pt(0.5)Pd(0.5) nanoparticle catalysts were studied in situ, during oxidizing, reducing, and catalytic reactions involving NO, O2, CO, and H2 by x-ray photoelectron spectroscopy at near-a...

متن کامل

Exploring the Synergistic Performance of a Pt-Rh/γ-Al2O3 Catalyst for the Reduction of NO with H2

Several researchers have shown that Pt-Rh bimetallic catalysts can perform synergistically for the NO/H2, NO/CO, CO/O2, and NO/CO/HC reactions [1-5]. Lakis and coworkers clarified some of the mystery surrounding the synergistic performance of Pt-Rh catalysts for the NO + H2 reaction by using analytical electron microscopy (AEM) to show that the synergistic performance of a Pt(95%)Rh(5%)/γ-Al2O3...

متن کامل

CATALYTIC REFORMING OF n-HEPTANE ON PLATINUM-TUNGSTEN SUPPORTED ON GAMMA-ALUMINA

The mono-metallic and bi-metallic catalysts have been prepared by impregnating with solutions containing a compound of H2PtCl6,WO3 and 1ml HCl (0.1 mol). It should be noted that the catalysts’ activity and selectivity have been determined under these conditions : 450-5000C ,and 15-25atm by H2. For converting n-heptane , the molar ratio H2/C7H16 is 5 , and LHSV is 1.5ml/h. It has been proved tha...

متن کامل

Experimental and Kinetic Study of CO Oxidation Over LaFe1-xCuxO3 (x=0, 0.2, 0.4, 0.6) Perovskite-Type Oxides

In this paper, catalytic oxidation of CO over the LaFe1-xCuxO3 (x= 0, 0.2, 0.4, 0.6) perovskite-type oxides was investigated. The catalysts were synthesized by sol-gel method and characterized by XRD, BET, FT-IR, H2-TPR and SEM methods. The catalytic activity of catalysts was tested in catalytic oxidation of CO. XRD patterns confirmed the synthesized perovskites to be single-phase perovskite-ty...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 1998